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Trans-Carbonylchloridobis[tris(4-chlorophenyl) phosphane]rhodium(I) acetone monosolvate

Show simple item record Omondi, Bernard O. Muller, Alfred Meijboom, Reinout Burgoyne, Andrew R. 2017-03-03T12:23:07Z 2017-03-03T12:23:07Z 2010 2017-03-03 2010
dc.identifier.citation Burgoyne A.R 2010, ‘Trans-Carbonylchloridobis[tris(4-chlorophenyl) phosphane]rhodium(I) acetone monosolvate’, Acta Crystallographica Section E, pp. m1380–m1381, doi:10.1107/S1600536810039814. en_US
dc.identifier.issn 1600-5368
dc.description.abstract The title compound, trans-[RhCl(C18H12Cl3P)2(CO)] C3H6O, contains an Rh(I) atom in a distorted square-planar coordination with a P—Rh—P angle of 175.27 (2) and Rh—P bond lengths of 2.3127 (4) and 2.3219 (4) A ° . The rhodium complexes link each other through weak intermolecular contacts between the acetone methyl groups and the carbonyl O atom. Interactions between the acetone solvent molecule and the Cl—Rh unit results in a reduced P—Rh—Cl angle of 86.675 (15) . en_US
dc.description.sponsorship National Research Foundation of South Africa (NRF) en_US
dc.format.extent 14 p. en_US
dc.format.medium PDF en_US
dc.language.iso en en_US
dc.relation.requires Adobe Acrobat Reader en_US
dc.subject Data-to-parameter ratio = 21.3 en_US
dc.subject wR factor = 0.069 en_US
dc.subject R factor = 0.026 en_US
dc.subject Mean (C–C) = 0.003 A° en_US
dc.subject Single-crystal X-ray study; T = 100 K en_US
dc.title Trans-Carbonylchloridobis[tris(4-chlorophenyl) phosphane]rhodium(I) acetone monosolvate en_US
dc.type Article en_US
dc.rights.holder National Research Foundation en_US

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