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[N,N-Bis(diphenylphosphino)propylamine- j2P,P0]dichloridoplatinum(II)

Show simple item record Cloete, Nicoline Visser, Hendrik G. Roodt, Andreas 2017-08-08T10:09:56Z 2017-08-08T10:09:56Z 2017-08 2010
dc.identifier.citation Cloete, N. et al. 2010 '[N,N-Bis(diphenylphosphino)propylamine- j2P,P0]dichloridoplatinum(II)' Acta Cryst. E66, m51–m52, doi:10.1107/S160053680905301X en_US
dc.identifier.issn 1600-5368
dc.description.abstract The Pt(II) atom in the title compound, [PtCl2(C27H27NP2)], has a highly distorted square-planar geometry, as evidenced by the P—Pt—P bite angle [72.4 (1) ]. The strain in the complex is further illustrated by the distorted tetrahedral angles of the P atoms, which range between 93.5 (1) and 122.2 (1) . It is of interest to note that the N atom has to adopt an almost planar geometry with the two P atoms and the C atom attached to it [it is displaced by 0.093 (2) A ° from the CP2 plane] in order to accommodate the steric bulk of the phenyl groups and the alkyl group of the ligand coordinated to the PtII centre. The molecules pack in horizontal rows across the bc plane. C— H Cl hydrogen bonds stabilize the crystal packing. en_US
dc.description.sponsorship South African National Research Foundation en_US
dc.format.extent 11 p. en_US
dc.format.medium PDF en_US
dc.language.iso en en_US
dc.publisher Acta Cryst en_US
dc.relation.requires Adobe acrobat reader en_US
dc.subject Diphenylphosphino en_US
dc.subject Dichloridoplatinum en_US
dc.title [N,N-Bis(diphenylphosphino)propylamine- j2P,P0]dichloridoplatinum(II) en_US
dc.type Article en_US
dc.rights.holder National Research Foundation en_US

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